Relationship between pore type and pore size of marine shale: An example from the Sinian–Cambrian formation, upper Yangtze region, South China

Abstract

To clarify the size distribution of different types of shale pores, nine Sinian–Cambrian shale samples from South China were examined using ion-milling, FE-SEM, nitrogen adsorption and mercury intrusion. Image-based point counting data indicated that nanopores are predominant, whereas pores larger than 1μm are absent. Organic matter-hosted pores dominate below 130nm, whereas intraparticle pores within carbonate, probably caused by dissolution, constitute most pores larger than 400nm. The small amount of residual intraparticle and interparticle pores associated with rigid minerals mostly range from 50nm to 250nm. A positive relationship was found between the TOC and total pore volume measured by nitrogen and mercury. The mercury volume of pores larger than ~300nm increased with increasing dolomite and decreasing clay mineral content. The statistics from image-analysis and the relationship between pore volume and shale components were in good agreement, indicating that different types of pores have their own relative restricted size range. Generally, intraP pores are larger than pores associated with rigid minerals, whereas the OM pores and interP pores associated with OM or clay are the smallest. Through a comparison with other less matured shale formations, the highly matured (equivalent vitrinite reflectance above 3%) Sinian–Cambrian shale in South China was characterized in this study as those with smaller interP pores, which is probably due to a stronger compacting effect.