Abstract
Polycyclic alkanes are not only the important components of high-density fuels, but also can be used to cool the overheating parts of hypersonic vehicle through catalytic endothermic dehydrogenation reaction. However, the dehydrogenation performances of cycloalkanes with different molecule structures vary widely. Herein, we investigated the effects of cycloalkane structures, including the length of branched chains, the number of branched chains, the number of rings, and the shape of rings, on the dehydrogenation performance. The results show that cyclohexane (CH) exhibits the best dehydrogenation performance (600 °C, 3 MPa) with >99% conversion, >99% benzene selectivity, and highest total heat sink of 4.47 MJ/kg. The branched chains, ring number and five-membered rings all have negative effects on dehydrogenation. Among them, the number of rings has the minimum negative impact. Moreover, we correlated the density, volumetric net heat of combustion (NHOC) and heat sink with the molecular structure of the cyclic alkanes and found that the polycyclic alkanes with low H/C ratio and high M have both high density, high volumetric NHOC and high heat sink. This work can provide guidance for development and design of advanced fuels for endothermic dehydrogenation.
Published Version
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