Reinvestigation of Magnetic Structures for the Thermally Induced States of CuFe1-xAlxO2(x=0.00, 0.02 and 0.05) Using a Four-Circle Neutron Diffractometer

Abstract

We have reinvestigated the effect of non-magnetic impurity on thermally-induced magnetic orderings in geometrically frustrated triangular lattice antiferromagnets CuFe 1- x Al x O 2 with x =0.00, 0.02 and 0.05, using a four-circle neutron diffractometer. Although we inferred in our previous work with a three-axis diffractometer that a proper screw type magnetic structure is realized in the intermediate-temperature (IM) phase of the samples with x =0.02 and x =0.05, in the present work we found that a sinusoidally amplitude-modulated magnetic structure with the magnetic moments canted by about 50° from the c axis toward the hexagonal direction is realized. These experimental findings suggest that the quasi-Ising magnetic orderings in CuFeO 2 are stabilized not with the strong Ising anisotropy expected from the Ising-like successive magnetic phase transitions in CuFeO 2 but with the small Ising anisotropy added to strongly competing exchange interactions.