Abstract
The design of highly ordered microporousmembranes has attracted considerable attentionsin the past decade because of their great interestsin basic research and industrial applications.Among many methods for fabricating microporouspolymeric film, the “breath figure” method [1–3]has attracted much attention due to the simple pro-cess. It employs solvent evaporative cooling onthe surface under humid conditions and waterdroplets are formed at the interface of the solutionand water vapor. Then, water droplets interactwith one another and are finally ordered in a hex-agonal lattice. In this paper, we prepared a seriesof amphiphilic diblock copolymer poly(vinyl phe-nol-
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