Abstract
The [1,2]- and [1,6]-rearrangements of s-octyl benzhydryl ether gave products in equal amounts whose formation occurred with 20% retention of configuration, and with complete recemization, for the [1,2]- and the [1,6]-products respectively; these results can be rationalized either by the formation of different non-equilibrating singlet radical pair intermediates, or by an important product formation after diffusion of the intermediate radical pairs.
Published Version
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More From: Journal of the Chemical Society, Chemical Communications
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