Regeneration and reuse of salt-tolerant zwitterionic polymer fluids by simple salt/water system

Abstract

Highly-efficient separation of adsorbent and pollutant from chemical sludge is urgent for the recycled materials and chemical resources and minimization of sludge production in industry. Herein, an effortless and cost-efficient salt/water system is developed for efficient zwitterionic polymer/dye separation from chemical sludge. To achieve this aim, a novel salt-tolerant zwitterionic polymer (STZP) is synthesized through etherifying 2-chloro-4,6-bis(4-carboxyphenyl amino)-1,3,5-triazine onto corn starch. It is found that “all-surface-area” adsorption of dye can be achieved by in-situ sol-gel transition of STZP. Spent polymer fluid and solid-state dye can be easily regenerated and separated from sewage sludge by a simple salt/water system. At a high NaCl concentration (225 g/L), the separation factor between zwitterionic polymer and dye is up to 50.4, which is 50 times larger than that of salt-free solution. More importantly, the regenerated polymer fluids exhibit an outstanding reusability ability and can maintain over 92.8% decoloration efficiency for dyeing effluent after multiple adsorption-desorption cycles. This study thus provides a technically feasible and economically acceptable strategy for the recycling and reuse of polymer from hazardous textile sludge waste, greatly promising to achieve zero emissions toward conventional adsorption units.