Abstract

Pre-treatment of poly (ethylene terephthalate) (PET) fibres with a strongly interacting solvent (dimethylformamide (DMF)) induces variation in the fibre structure and improves its optical anisotropy. As a result, variations in the optical properties have been demonstrated. The values for refractive indices in the two principal vibration directions, along and across the fibre axis, and birefringence values are obtained using the two-beam interference Pluta microscope. They increase with increase in time of both solvent and thermal treatments. Increases in the crystallinity values with the time of thermal treatment have been reported. Optical and structural parameters such as mean polarizability per unit volume, molar refractivity and surface reflectivity have been also calculated. The resultant parameters reflect good effect of the solvent and thermal treatments on the molecular orientation in PET fibres. Illustration can been given by graphs and microinterferograms.

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