Abstract
The behavior of sodium oxide bronzes in contact with sodium-conducting solid electrolytes in atmospheres of oxygen, carbon dioxide, hydrogen sulfide, and humid air was investigated. The exchange currents at the NaxCoOy/NASICON interface was determined. It is shown that among the sodium-cobalt oxide bronzes the β-phase of the composition Na0.6CoO2 is the most reversible one (exchange current 236 µA/cm2).
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