REE and trace element mobility during the transformation of basalt to laterite and bauxite, Payas Province, Türkiye

Abstract

The bauxites of the Payas area in the eastern Mediterranean region of Turkey occur as a stratigraphically continuous layer between Early and Late Cretaceous shallow marine carbonates. The laterites represent an in situ formation and mark a key stratigraphic layer in the region. Bauxite pockets are also present in the laterites, formed from the reworking of the laterites and accumulated in depressions in the karst terrain. Therefore, bauxite occurrences are found locally in this stratigraphic layer. The parental rock was a Ti-rich basalt that is compositionally similar to Hawaiian basalts, as indicated by petrographic features and distinctive trace element composition (Zr/TiO2 and Nb/Y). The behavior of elements during the lateritization and bauxitization processes was interpreted using the composition of the Hawaiian basalts with the iron laterite and Ti-rich bauxites of the Payas Region. During lateritization, Fe, Al, Ti, Cr, Nb, and Ta, were largely immobilie while REE and other trace elements, except for Rb, Ni, Co, and Pb were significantly removed. Approximately 75 % of the REE were removed at the end of the bauxitization and/or transportation of the lateritic soil into the karstic depressions. REE were not equally mobile with La to Ce and Lu to Yb having a relatively lower mobility than highly mobile middle REE. During the transformation of laterite to bauxite, low mobility elements such as Ti, Nb, Th, Cr, Hf, and Sn were enriched in the bauxite phase. In comparison to other elements, Rb, As, Pb, Mo, and Ni were strongly removed from the lateritic material during the bauxitization processes. The transfer of MREE during lateritization and bauxitization would have resulted in the enrichment of both light and heavy REE (concave pattern) in contemporaneous seawater. In other words, silicate weathering periods on land should be marked by a concave REE pattern with positive Eu anomaly in marine sediments throughout the geological period.