Abstract
The hydrogenation of acetone, methyl ethyl ketone, isopropyl methyl ketone and cyclohexanone was investigated in the presence of catalysts prepared in situ in basic methanol solution from Rh 2Cl 2(C 8H 14) 4,rhodium(II) and rhodium(III) complexes and suitable ligands: 1,10-phenanthroline and 2,2'-dipyridyl. The most effective catalytic system was prepared from [Rh 2Cl 2(HCOO) 2(dipy) 2]·2H 2O and 2,2'-dipyridyl in basic methanol solution.
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