Abstract
Durch basenunterstützte Reduktion einer Palladium(II)-Vorstufe wurde der erste Palladium(I)-NHC-Komplex (NHC=N-heterocyclisches Carben) in hoher Ausbeute hergestellt und isoliert. Die Position des einzigartigen terminalen Hydridliganden (siehe Bild; PdI cyan, H weiß, N blau) wurde durch Neutronenbeugung am Einkristall bestimmt, und das fluktuierende Verhalten des Komplexes in Lösung wurde untersucht. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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