Abstract

Conductive polymer composites, consisting of multi-walled carbon nanotubes and a small amount of carbonyl iron particles, are fabricated under an ordinary magnetic field, to form anisotropic microstructures. The alignment of carbonyl iron particles will change the structure of a multi-walled carbon nanotube network and consequently the electrical properties of conductive polymer composites. In this research, we focus on the effect of the anisotropic microstructures on the electrical properties of the composites, especially on the percolation threshold and electrical resistivity. Monte Carlo simulations for three-dimensional stick percolation systems are performed to predict the percolation threshold of the anisotropic conductive polymer composites in terms of orientation distribution of multi-walled carbon nanotubes. In addition, an eight-chain model is proposed to investigate the influence of the anisotropic distribution of multi-walled carbon nanotubes on the electrical resistivity of the composites. It is predicted that the percolation threshold could be reduced from 0.70 vol% for the isotropic composites to 0.49 vol% for the anisotropic composites. Meanwhile, the electrical resistivity of the anisotropic composites is about 10%–20% of that of the isotropic composites when the volume fraction of multi-walled carbon nanotubes is higher than the percolation threshold. The simulation results are compared with the experimental study results that show a very similar behavior although there are some deviations in the values.

Full Text
Published version (Free)

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call