Abstract
The redox reaction between divalent and trivalent iron species in binary and ternary molten salt systems consisting of 1-ethyl-3-methylimidazolium chloride (EMICl) with iron chlorides, FeCl 2 and FeCl 3, was investigated as a candidate of the half-cell reactions of novel rechargeable redox batteries based on low temperature molten salt systems. A reversible one-electron redox reaction between divalent and trivalent iron species was observed on a platinum electrode in EMICl–FeCl 2–FeCl 3 system at 130 °C. The voltammetric data indicated that divalent and trivalent iron species were FeCl 3 − and FeCl 4 − complex anions, respectively. Combined with another proper redox couple, this molten salt system can be utilized in a rechargeable redox battery on account of its low melting temperature and reversible redox reaction.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
