Abstract

Due to the development of new photovoltaic technologies, there is a need to research new recycling methods for these new materials. The recovery of metals from photovoltaic (PV) modules would reduce the consumption of raw materials. Therefore, the development of recycling technologies for used and damaged modules of newer generations is important for environmental reasons. The aim of the research is to shed light on the nature of the chemical reactions that occur in recycling technology for second-generation photovoltaic modules. This work is focused mainly on cells made of Cadmium Telluride (CdTe). It was proven that prior thermal delamination was necessary. Moreover, an improvement in understanding of the recovery process depending on used leaching solution was achieved.

Highlights

  • Modules based on crystalline silicon and modules made with thin-film technologies must be recycled in three stages: delamination, material removal, and material recovery

  • Delamination plays a key role in the recycling process

  • Attempts etch the themilled milledfragments fragmentsofof thin-film module made of Cadmium Telluride (CdTe)

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Summary

Introduction

Modules based on crystalline silicon and modules made with thin-film technologies must be recycled in three stages: delamination, material removal, and material recovery. In both cases, delamination plays a key role in the recycling process. For the thin-film modules, material removal and recovery are harder because it is not possible to separate the cell plates and reuse them [1]. It is a moot point whether recycling of the thin-film modules is profitable because the semiconductor material constitutes less than

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