Abstract
The pentanuclear compound [V(II)(tmphen)2]3[Mo(III)(CN)6]2 (tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline) exhibits a record antiferromagnetic exchange coupling constant of J(V-Mo) = -114 cm(-1). This is the first example of a heterobimetallic cyanide compound with such strong magnetic coupling.
Published Version
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