Abstract

The rational design of anode materials plays a significant factor in harnessing energy storage. With an in‐depth insight into the relationships and mechanisms that underlie the charge and discharge process of two‐dimensional (2D) anode materials. The efficiency of rechargeable batteries has significantly been improved through the implementation of defect chemistry on anode materials. This mini review highlights the recent progress achieved in defect chemistry on 2D materials for advanced rechargeable battery electrodes, including vacancies, chemical functionalization, grain boundary, Stone Wales defects, holes and cracks, folding and wrinkling, layered von der Waals (vdW) heterostructure in 2D materials. The defect chemistry on 2D materials provides numerous features such as a more active adsorption sites, great adsorption energy, better ions‐diffusion and therefore higher ion storage, which enhances the efficiency of the battery electrode.

Highlights

  • Owing to the widespread consumption of fossil fuels, the two main global challenges facing the world nowadays consist of environmental-pollution and energy issues

  • Many defect chemistry models in the framework of 2D materials have a considerable potential to significantly enhance the functionality of 2D materials over a range of energy storage technologies, metal-ion batteries, the amount of published papers or-reviews devoted to different defect chemistry on 2D materials is growing steadily

  • The 2D-defect chemistry that is typical for von der Waals (vdW) and inter-layer materials, including holes-craks, folding-wrinkling, ripping, and vdW-heterostructure, can occur in 2D materials, these will not be covered in this mini-review, a few defect type related in interlayer materials are significant and will be outlined shortly

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Summary

Introduction

Owing to the widespread consumption of fossil fuels, the two main global challenges facing the world nowadays consist of environmental-pollution and energy issues. His PhD work focus on unifying energy harvesting through 2D materials modelling, including energy conversion and storage applications. Deobrat Singh is a postdoctoral researcher at Materials Theory Group, Department of Physics and Astronomy, Uppsala University, Sweden under the supervision of Prof. His research interest spans over a broad range, wherein he employs diverse computational tools to explore various significant scientific problems related to nanomaterials, catalysis, sensors, molecular electronics, materials for energy storage including solar cells, perovskites, batteries, thermoelectric devices and other applications of novel twodimensional monolayer/multilayer materials He has published more than 67 scientific papers in peer-reviwied journals (with a total citations ~ 560; hindex = 11) covering these topics. The readers will be able to gain a deeper www.chemasianj.org understanding about the critical role of defect engineering in

Defect chemistry in 2D materials
Zero-Dimensional defects in 2D materials
One-Dimensional defects in 2D materials
Two-Dimensional defects in 2D materials
Defective 2D anode materials for rechargeable Batteries
Doping defects for MIBs
S W defects for MIBs
Vacancies defects for MIBs
Interlayer defects for MIBs
Methods
Summary and outlook
Conflict of Interest
Full Text
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