Abstract
AbstractIt is well‐known that solvent is one of the most important factors that affect chemical reactions. This factor is more noticeable and impressive in the asymmetric reactions where the effective interaction of reactants and the creation of a uniform chiral environment is necessary. Nevertheless, when reactions are carried out in the absence of solvent, some privileged advantages such as easy work up, short reaction time, lack of waste solvents, and following the green chemistry principles, are appeared. Therefore, according to the importance of asymmetric synthesis and green chemistry, solvent‐free asymmetric catalysis can act as a considerable and necessary subject in synthetic chemistry. In this review, we have a survey on the solvent‐free asymmetric synthesis by the use of either homogeneous or heterogeneous chiral catalysts.
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