Recent advances in solid-state NMR of zeolite catalysts.

Abstract

Zeolites are important inorganic crystalline microporous materials with a broad range of applications in the areas of catalysis, ion exchange, and adsorption/separations. Solid-state nuclear magnetic resonance (NMR) spectroscopy has proven to be a powerful tool in the study of zeolites and relevant catalytic reactions because of its advantage in providing atomic-level insights into molecular structure and dynamic behavior. In this review, we provide a brief discussion on the recent progress in exploring framework structures, catalytically active sites and intermolecular interactions in zeolites and metal-containing ones by using various solid-state NMR methods. Advances in the mechanistic understanding of zeolite-catalysed reactions including methanol and ethanol conversions are presented as selected examples. Finally, we discuss the prospect of the solid-state NMR technique for its application in zeolites.