Abstract
Waste-centred-bioenergy generation have been garnering interest over the years due to environmental impact presented by fossil fuels. Waste generation is an unavoidable consequence of urbanization and population growth. Sustainable waste management techniques that are long term and environmentally benign are required to achieve sustainable development. Energy recovery from waste biomass via dark fermentative hydrogen production is a sustainable approach to waste management. Vegetable waste is generated in plenty over the food supply chain and being a rich source of carbon and other nutrients it has been studied for production of biohydrogen. This review aims to offer a comprehensive overview on the potential of vegetable waste as a feedstock for dark fermentative biohydrogen production. The hydrogen output from dark fermentative process is lower and additional strategies are required to improve the production. This review addresses the challenges generally encountered during dark fermentative hydrogen production using vegetable waste and the importance of methods such as bioaugmentation and application of extremophiles for process enhancement. The role of machine learning in the field of biohydrogen production is briefly discussed. The application of dark fermentative effluents for secondary valuable product generation and its contribution to the biohydrogen biorefinery is discussed as well.
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