Abstract

The photo-induced decarbonylation of compounds of the type (η 5-C 5Me 4R)-Mo(CO) 2(NO) (R = Me, Et) in the presence of acyclic olefins or cycloolefins yields the corresponding alkene complexes. Because of the chiral metal center, prochiral olefins are incorporated into diastereomeric complexes,s which were identified by spectroscopic means.

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