Abstract
We have developed what we believe to be the very first a priori prediction technique for the gasification reactivity of coal char. With this method the gasification reactivity of a coal char as function of temperature can be predicted from a single temperature programmed desorption (TPD) experiment following mild gasification at a single temperature (Calo et al., 1989; Hall and Calo, 1990a). This approach has been demonstrated for C0{sub 2} gasification of coal chars where the gasification reactivity is controlled by the thermal desorption of oxygen surface complexes formed during gasification. This approach may be extended to other oxidant species, such as steam, and carbon-hydrogen complexes for hydrogen gasification as well. In the current report, we present a summary of the work that has been conducted to date in constructing a new TGA/TPD-MS experimental system which provides us with the capability of simultaneous monitoring of transient sample mass data, as well as gas phase composition during thermal desorption experiments. In addition, we present some steam reactivity data obtained with another TGA (Cahn 113 system) which has been modified for steam gasification experiments.
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