Abstract
The chemical and physical properties of a neutral nickel(II) complex ion containing a Ni, 2N, 3C quasi-aromatic ring are presented. Electrophilic substitution at the C12 position of the ring readily occurs producing highly stable compounds whose identity has been determined by single crystal X-ray diffraction. The ring is capable of conjugation with aromatic molecules giving substances with very high visible light absorption. The platinum(II) analogue has been prepared and shows similar reactivity.
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