Reactivity of metal dioxo complexes.

Abstract

Metal dioxo chemistry and its diverse reactivity are presented with an emphasis on the mechanisms of reactivity. Work from approximately the last decade is surveyed and organized by metal. In particular, the chemistry of cis-dioxo metal complexes is discussed at length. Reactions are grouped by generic type, including addition across a metal oxo bond, oxygen atom transfer, and radical atom transfer reactions. Attention is given to advances in deoxygenation chemistry, oxidation chemistry, and reductive transformations.