Abstract
The title reaction was studied in a crossed-beam apparatus. The dependencies of both integral and doubly differential cross sections on the initial collision energies were measured. From the appearance of the excitation function, a barrier height of ∼ 3 kcal/mol was deduced, which is lower than the currently accepted value by as much as 1 kcal/mol. Both the product speed and angle distributions show an anomalous dependence on the initial collision energies. These results can be reconciled by taking into account the steric effects and the adiabaticity between CN rotation and HCN bend.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
