Abstract
Rate laws and rate constants are reported for reactions of several low-spin iron(II) complexes with hydroxide ion in methanol-water solutions. The dependence of the form of the rate law and of reactivity on ligand type and on substituent nature is discussed. The pattern of reactivity for a range of compounds with hydroxide ion in methanol-water mixtures is compared with the reactivity pattern for analogous reactions in dimethyl sulphoxide-water mixtures.
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