Abstract
The reactions of germylenes with nitrosobenzene lead to nitrene and ▪ intermediates via the zwitterionic form of the appropriate germaoxa-aziridines. Interactions between the germylenes and the nitrene generated in the reactions give new ▪-intermediates. The formation of germaoxa-azetidine is observed in the insertion reaction of germylene into the oxaziridine ring, in the 1,3-cycloaddition of germylene to the nitrone which is an isomer of the oxaziridine and also in the dehydrochlorination reaction of C-germylated hydroxylamines ▪. The β-elimination process from germaoxa-azetidines leads to imine and ▪ intermediates
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