Abstract

N-Methyl-2,2-diphenyl-2-germyl azetidine was prepared by the reaction of MeNLi 2 or MeNH 2 and 1-chloro-2-diphenylchlorogermylethane. The germylazetidine leads, through a β-elimination process, to the corresponding germaimine which has been characterized by insertion reactions into the GeN bond of both the germylazetidine and dimethyl(triethylgermyl)amine.

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