Abstract
Structure of radical anions of “bridged” amidoesters MeOOC(CH2)nCONMe2 (n=0–3) generated by X-ray irradiation was investigated by EPR, optical absorption spectroscopy and quantum-chemical calculations. Amidoester-0 (n=0) has positive calculated electron affinity and the corresponding delocalized radical anion is stabilized independent of matrix polarity. Meanwhile, for amidoesters with n=1–3 groups possessing apparently negative intrinsic electron affinity the role of matrix in stabilization of the corresponding radical anions becomes crucial. Two types of the localized radical anions were observed in the latter case.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
