Year-end Sale % OFF 
Abstract
Abstract The reactivity of some di(1-pyrazolyl)propanecopper (II) complexes with various anions in aqueous solutions has been studied. Di(1-pyrazolyl)propanecopper (II) chloride, Cu(Me2CpZ2)Cl2, reacts readily with pseudohalide ions to give complexes of the type, Cu(Me2Cpz2)Z2 (Z=SCN−, NCO−, N3 −). With PF6 − and BPh4 − anions, complexes of the type [Cu(Me2Cpz2)2X] Y (Y=PF6 −, X=Cl−, Br− and NO3 −; Y=BPh4 −, X=Cl−) are formed. However, the reaction of Cu(Me2Cpz2)Cl2 with acetylacetonate (acac), dialkyldithiocarbamate (S2CNMe2, S2CNEt2), or poly(1-pyrazolyl)borate (H2BPz2 −, HBpz3 −) anions leads to the displacement of Me2CPz2 and the subsequent formation of neutral Cu(acac)2, Cu(S2CNR2)2, Cu(H2Bpz2)2 and Cu(HBpz3)2 complexes. Reaction products have been characterised by elemental analysis, magnetic moments and infrared spectral measurements.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
