Reaction of Hydroxyl Radicals with C4H5N (Pyrrole): Temperature and Pressure Dependent Rate Coefficients

Abstract

Absolute (pulsed laser photolysis, 4-639 Torr N(2) or air, 240-357 K) and relative rate methods (50 and 760 Torr air, 296 K) were used to measure rate coefficients k(1) for the title reaction, OH + C(4)H(5)N → products (R1). Although the pressure and temperature dependent rate coefficient is adequately represented by a falloff parametrization, calculations of the potential energy surface indicate a complex reaction system with multiple reaction paths (addition only) in the falloff regime. At 298 K and 760 Torr (1 Torr = 1.33 mbar) the rate coefficient obtained from the parametrization is k(1) = (1.28 ± 0.1) × 10(-10) cm(3) molecule(-1) s(-1), in good agreement with the value of (1.10 ± 0.27) × 10(-10) cm(3) molecule(-1) s(-1) obtained in the relative rate study (relative to C(5)H(8), isoprene) at this temperature and pressure. The accuracy of the absolute rate coefficient determination was enhanced by online optical absorption measurements of the C(4)H(5)N concentration at 184.95 nm using a value σ(184.95nm) = (1.26 ± 0.02) × 10(-17) cm(2) molecule(-1), which was determined in this work.