Abstract
Reaction of [(κ 2-P,N)–Me 2N(CH 2) 3PPh 2]PtMe 2 [(P∩N)PtMe 2] with HSiR 3 (triethylsilane or diphenylmethylsilane) results in the formation of MeSiR 3 and the methyl silyl complexes (P∩N)Pt(Me)SiR 3. In the early stages of the reaction, the hydrido complex (P∩N)Pt(Me)H is additionally observed. In the reaction of HSiMePh 2, the rearranged complex (P∩N)Pt(Ph)SiMe 2Ph is also formed. The reactivity of the complexes (P∩N)PtMe 2 is influenced by the kind of chelating P∩N ligand and appears to depend on how easily the amino group is de-coordinated.
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