Abstract
Thermal reaction of (η5-C5H5)Rh(C2H4)(H)(SiR3) with R′3SiH (R, R′= Et, Me) generates the sterically hindered poly(silyl) complexes (η5-C5H5)Rh(SiR′3)2(SiR3)H, some of which contain an η2-silane ligand; these complexes undergo silyl migrations with an excess of silane and also prove photosensitive.
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