Abstract
Abstract Linear 1/1 adducts and oxazinone derivative were obtained by the reaction of N-trimethylsilyl- and -stannyl(diphenylmethylene)amine; Ph2C=N–MMe3 (M=Si, Sn) with diketene. Consecutive demetallation reaction by ethanethiol for the organostannyl 1/1 adduct, and by methanol for the organosilyl 1/1 adduct gave a piperidine derivative and an oxazinone derivative, respectively.
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