Abstract
Aryl(diarylphosphoryl)methanols reacted with alkyl propiolates under mild conditions (triethylamine, THF, 22‒25°C), to give the corresponding anti-Markovnikov adducts, alkyl (E)-3-[aryl(diarylphosphoryl) methoxy]prop-2-enoates, with high yields (84–90%) and regio- and stereoselectivity.
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