Abstract
Ketene silyl acetals and allyl acetates react in the presence of Pd(0) phosphine complexes to yield allylated products and cyclopropane derivatives. The latter are formed through nucleophilic attack of the silyl enolate on the central carbon atom of the allyl group. The influence of the structure of the silyl enolate, substitution of the allyl group and phosphorus ligand has been investigated.
Published Version
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