Reaction Mechanism and Microstructure Development of Zr–Si Alloyed Melt‐Infiltrated ZrC‐Modified C/C Composite

Abstract

ZrC ceramic modified‐C/C composite is prepared by a quick and low‐cost reactive melt infiltration process with a Zr‐Si8.8 alloy. Reaction kinetics and mechanism of pyrolytic carbon with the infiltrated Zr‐Si8.8 alloy are investigated. A continuous ZrC layer is found to be formed around pyrolytic carbon due to the in situ reaction and its thickness parabolically increases with an increase in reaction time period. Zr concentration in the alloyed melts decreases due to the reaction between Zr and pyrolytic carbon and Zr2Si phase precipitates from the residual alloyed melts. A model for the growth of ZrC layer is established to describe the reaction kinetics of pyrolytic carbon with Zr‐Si8.8 alloy. The calculated thickness of the reaction‐formed ZrC layer is in good agreement with the experimental data. Based on the Arrhenius equation, the activation energy of the reaction between carbon and Zr‐Si8.8 alloy is 313.2 KJ/mol, smaller than that of the reaction between carbon and pure zirconium. The microstructure of the reactive melt‐infiltrated ZrC‐modified C/C composite is characterized by optical microscope, SEM, EDS, XRD, and TEM. The mechanism of the reaction between pyrolytic carbon and Zr‐Si8.8 alloy is discussed on the basis of the characterization results and phase diagram. A schematic is proposed to understand the reaction mechanism between pyrolytic carbon and Zr‐Si8.8 alloy and microstructure development of the ZrC‐modified C/C composite.