Abstract
The structure of an intermediate formed by reaction of nitrogen dioxide with hexacyanoferrate(III) ion is deduced to be a bridged binuclear complex, [Fe2(CN)9(NO)2]3–, on the basis of stoicheiometric, i.r., and Mossbauer evidence. A linear nitrosyl bridge is suggested. The other products, ammonia, carbon dioxide, and cyanogen all suggest that nitrogen dioxide oxidises a cyanide ligand to cyanate, which subsequently decomposes. The intermediate is formed by a disproportionate reaction between two of the [Fe(CN)6]3––NO2 adducts.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Journal of the Chemical Society, Dalton Transactions
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.