Abstract
Optical and C-13 NMR examinations of concentrated solutions of poly-γ-benzyl-L-glutamate (PBLG) in a mixed solvent system containing a denaturant acid, show that this polymer liquid crystal has both a low and high temperature isotropic phase. The latter is due to thermal disruption of long-range orientational order of the elongated macromolecules. The former re-entrant isotropic phase is a result of an intramolecular helix to random coil transition, which leads to a macromolecular conformation inconsistent with liquid crystallinity.
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