Rational Design of the First Ammonium Magnesium Borate with Deep-Ultraviolet Cutoff Edge and Moderate Birefringence and Further Investigation into the Nature of Ammonium in the Borate System.

Abstract

Through the rational design of the experimental method, the first combination of ammonium and magnesium in the borate system was successfully achieved. In this paper, a case of ammonium magnesium borate, (NH4)2{Mg(H2O)2[B6O7(OH)6]2}·2H2O, was successfully synthesized by a mild hydrothermal method at a relatively low temperature. A brief review was performed to show the participation of NH4+ in the recent development of optical materials. By discussing the optimum synthesis method of ammonium-containing borates and the main factors affecting the dimensionality of B-O anionic groups in their structures, the design strategy for synthesizing ammonium-containing borate and adjusting its structure has been put forward. Relevant experimental measurement results and the first-principles calculation results show that the title compound has a deep-UV cutoff edge (<200 nm) and moderate birefringence (Δncal. = 0.064 @546 nm), which indicates its potential application in the deep-UV region.