Abstract

Bis(phenylcarbamoyl)-functionalized tetraoxacalix[2]arene[2]triazine host molecule bearing incorporated hydrogen bonding motifs in the proximity of the anion–π interaction domain was synthesized efficiently. The tailor-made macrocyclic host acts as a multivariate receptor to selectively recognize H2PO4− anion through cooperative anion–π and anion–hydrogen bond interactions.

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