Abstract
Kinetics and mechanisms of substitution reactions of square-planar platinum(II) dithiolato-complexes [Pt(S–S)2]2–[S–S2–=(NC)2C:CS22–(cet), S(NC)C:C(NC)S2–(ct), NO2CH:CS22–(net), S(O)C:C(O)S2–(dta), NC–N:CS22–(cimd), and NC(Ph)C:CS22–(npet)], with both uni- and bi-dentate nucleophiles have been studied in aqueous solution. The reactions are second order, first order in substrate and first order in nucleophile. Activation parameters have been measured for a number of the reactions. The results permit a comparison of the reaction mechanisms and relative reactivities of dithiolato-complexes of nickel, palladium, and platinum.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Journal of the Chemical Society, Dalton Transactions
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.