Abstract
Rate constants for 6- exo cyclization of the 7,7-diphenyl-6-heptenyl radical ( 3) in benzotrifluoride (BTF, PhCF 3) were determined by laser flash photolysis, and radical clock 3 was used in competition kinetic studies for determination of rate constants of reactions of the fluorous tin hydride reagent tris(2-(perfluorohexyl)ethyl)tin hydride with primary alkyl radicals.
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