Abstract

Kinetic parameters for the IMDAF reaction of 1b and 2b were compared: k( lb)/k( 2b = 60. The activation parameters for the cyclization of 1b, ΔH≠ = 83.9 kJ/mol and ΔS≠ = −71.7j/(mol.K), do not suggest an entropic basis for acceleration.

Full Text
Published version (Free)

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call