Rapid Synthesis of Flower-Like ZnO Nanostructures

Abstract

Flower-like ZnO nanostructures were prepared via microwave assisted heating in the presence and absence of ionic liquid (IL). X-ray diffraction analysis (XRD), Scanning electron microscopy SEM and room temperature photoluminescence (PL) spectra have been employed for characterization of the products. The SEM image illustrates the surface of flower-like ZnO prepared in the presence of IL is not smooth and consists of nanoparticles with grain size of about 48 nm. PL spectra of flower-like ZnO in absence and presence IL reveal similar photoluminescence features: a strong UV, weak blue and green-yellow emissions peak at a bout 393 nm, 448 nm and 583 nm respectively. The strong UV photoluminescence and the weak green emission indicate the good crystallization quality of the flower-like nanostructure. The results show that imidazolium-based IL can be used as template for achieving very high level control over the size and shape of nanostructures. The approach developed in this work can potentially be used as a viable method for making various other uniform nanostructures in the presence of IL. This method is simple, fast, low-cost and suitable for large-scale production of ZnO nanostructures.