Abstract
Hydrothermal treatment has been widely employed for material synthesis and modification. In this work, with the help of the homemade microreactor, a rapid high-temperature hydrothermal post treatment (RHTHTPT) process with fast heat transfer and short processing time was elaborately designed for graphitic carbon nitride (g-C 3 N 4 ). Taking advantage of high temperature and short duration time during RHTHTPT process, the RHTHTPT-derived g-C 3 N 4 reached up to a high product yield over 80%. The RHTHTPT-derived g-C 3 N 4 showed an enhanced photocatalytic H 2 -evolution activity about 5.1 times that of pristine g-C 3 N 4 under visible-light irradiation ( λ > 400 nm). With systematic characterizations and the tracking of gas-liquid-solid products by RHTHTPT, it was found that the RHTHTPT could effectively enlarge the specific surface area to increase the active sites for photocatalytic H 2 -evolution reaction, abundant amino groups and the insertion of oxygen-containing functional groups in the surface of g-C 3 N 4 could realize efficient carriers separation, both of which gave rise to the improved photocatalytic H 2 -evolution performance. This work develops a promising hydrothermal strategy to regulate the in-plane structure of g-C 3 N 4 and brings a deeper understanding for the correlation between RHTHTPT-induced structure modification with photocatalytic ability, and therefore further provides some guidelines for directionally designing the special structures of g-C 3 N 4 as well as other potential materials by hydrothermal modification. • A rapid high-temperature hydrothermal post treatment (RHTHTPT) was developed. • RHTHTPT-derived g-C 3 N 4 reached up to a high product yield over 80%. • RHTHTPT enlarged surface area and inserted O-containing functional group in g-C 3 N 4 . • RHTHTPT-derived g-C 3 N 4 showed an enhanced photocatalytic H 2 -evolution activity.
Published Version
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