Rapid determination of impurities in carbon dioxide for food by gas chromatography

Abstract

This article describes the experimental principle and method of rapid determination of carbon monoxide, methane, propane, total hydrocarbon, methanol, ethylene oxide, acetaldehyde, vinyl chloride, benzene, and other common impurities in carbon dioxide by gas chromatograph. By using food additive carbon dioxide as a sample, the rapid analysis conditions, such as chromatographic column, valve switching time, and column box temperature control, were optimized. The retention time of impurity components in food additive carbon dioxide was determined using the external standard method. The relative standard uncertainty of CH4, C3H8, CO, CH3OH, CH2CH2O, CH3CHO, CH2CHCl, and C6H6 analysis is within 3% by using the established analytical method proposed in this article, which is equivalent to the national standard GB 1886.228-2016. The linear correlation coefficient r is greater than 0.9995, and the linear error is not greater than 2.0, indicating excellent linearity. In the meantime, in the case of 6 consecutive sample injections, the detection time is shortened by nearly three times. The experimental results show that the analytical method established in this article is suitable for the rapid determination of impurities in carbon dioxide for food, which can improve the accuracy of experimental results and work efficiency.