Abstract

The absolute Raman cross section of the methane ν1 line at 266 nm has been determined to be (6.2±1.5)×10-33 m2/(mol·sr) with Raman-induced Kerr effect spectroscopy. The use of polarization detection is effective in improving the signal-to-noise ratio in a measurement using two pulsed lasers with a relatively large shot-to-shot fluctuation.

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