Abstract
The title xanthone (systematic name: 3,6,11-trihydroxy-1,1-dimethyl-2,3-dihydrochromeno[2,3-f]chromen-7-one monohydrate), known as pruniflorone N, crystallized as a monohydrate, C18H16O6·H2O. The three ring systems of the xanthone skeleton are approximately coplanar, with an r.m.s. deviation of 0.0270 (1) Å from the plane through the 14 non-H atoms. The O atoms of the two hydroxy substituents on the benzene rings also lie close to this plane, with deviations of 0.019 (1) and 0.070 (1) Å. The 2′-hydroxy-4′,4′-dimethylpyran ring is disordered over two positions with a 0.798 (3):0.202 (3) site-occupancy ratio. An intramolecular O—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal, the xanthone and water molecules are linked into a three-dimensional network by O—H⋯O hydrogen bonds and weak C—H⋯O interactions. π–π interactions, with centroid–centroid distances of 3.5982 (7), 3.6081 (7) and 3.6456 (7) Å, are also observed.
Highlights
The title xanthone, known as pruniflorone N, crystallized as a monohydrate, C18H16O6H2O
The 20 -hydroxy-40,40 -dimethylpyran ring is disordered over two positions with a 0.798 (3):0.202 (3) siteoccupancy ratio
H atoms treated by a mixture of independent and constrained refinement max = 0.71 e Å3
Summary
Faculty of Traditional Thai Medicine, Prince of Songkla University, Hat-Yai, Songkhla 90112, Thailand, bDepartment of Chemistry, Faculty of Science, Prince of Songkla University, Hat-Yai, Songkhla 90112, Thailand, cX-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia, and d
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have