Abstract
Mixtures of silver- or copper(I)-halides with mercury(II)-chalcogenides were investigated by X-ray and thermal methods. The phase relations of the systems AgCl-HgS and CuCl-HgS were determined. In the first system the new quaternary chalcogenide-halides AgHg 2S 2Cl and AgHgSCl were found. AgHgSCl crystallizes in the orthorhombic system with the lattice parameters a = 1024(1), b = 1273(3) and c = 902,3(5) pm. CuHg 2S 2Cl was observed in the system CuCl-HgS. The compound crystallizes in the tetragonal system with the lattice parameters a = 2644,4(3) and c = 409,2(1) pm.
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