Quasi-incompressible multi-species ionic fluid models

Abstract

In traditional hydrodynamic theories for ionic fluids, conservation of mass and linear momentum is not properly taken care of. In this paper, we develop hydrodynamic theories for viscous, ionic fluids of N ionic species enforcing mass and momentum conservation as well as considering the size effect of the ionic particles. The theories developed are quasi-incompressible in that the mass-average velocity is no longer divergence-free whenever there exists variability in densities of the fluid components, and the theories are dissipative. We present several ways to derive the transport equations for the ions, which lead to different rates of energy dissipation. The theories can be formulated in either number densities, volume fractions or mass densities of the ionic fluid components. We show that the theory with the Cahn-Hilliard transport equation for ionic species reduces to the classical Poisson-Nernst-Planck (PNP) model with the size effect for ionic fluids when the densities of the fluid components are equal and the entropy of the solvent is neglected. It further reduces to the PNP model when the size effect is neglected. A linear stability analysis of the model together with two of its limits, which are the extended PNP model (EPNP defined in the text) and the classical PNP model (CPNP) with the finite size effect, on a constant state and a comparison among the three models in 1D space are presented to highlight the similarity and the departure of this model from the EPNP and the CPNP model.